Noble Metals Functionalized on Graphene Oxide Obtained by Different Methods—New Catalytic Materials

In recent years, research has focused on developing materials exhibiting outstanding mechanical, electrical, thermal, catalytic, magnetic and optical properties such as graphene/polymer, graphene/metal nanoparticles and graphene/ceramic nanocomposites. Two-dimensional sp2 hybridized graphene has become a material of choice in research due to the excellent properties it displays electrically, thermally, optically and mechanically. Noble nanomaterials also present special physical and chemical properties and, therefore, they provide model building blocks in modifying nanoscale structures for various applications, ranging from nanomedicine to catalysis and optics. The introduction of noble metal nanoparticles (NPs) (Au, Ag and Pd) into chemically derived graphene is important in opening new avenues for both materials in different fields where they can provide hybrid materials with exceptional performance due to the synergistical result of the specific properties of each of the materials. This review presents the different synthetic procedures for preparing Pt, Ag, Pd and Au NP/graphene oxide (GO) and reduced graphene oxide (rGO) composites.


Introduction
Polymer electrolyte membrane fuel cells (PEMFCs) represent one of the top researched power generation devices that convert the chemical energy of hydrogen directly into electricity [1]. Because this technology is clean as well as efficient, it provides an option for applications such as power generation on a large scale, co-generation of power and heat, backup and off-grid energy sources as well as transportation and mobile applications. Serving as one of the main problems that requires solving is the inferior kinetics of the oxygen reduction reaction (ORR) as well as the fuel cell reactions, which require a significant number of precious metals, leading to high costs of production. Poor performance and robustness of the catalysts being used as part of the electrodes is another significant problem to solve for PEMFCs [2]. Various materials and methods have also been proposed to solve these problems. Thus, one approach in this regard was replacing the carbon black in the catalyst layer with graphene. Over the last few years, numerous studies were carried out to evaluate the potential of using graphene-based materials in energy applications. Their large surface area, outstanding mechanical characteristics and superior electrical conductivity coupled with the workability of graphene have been the reasoning behind this attention [1]. Globally, there is a growing demand for nanostructured materials, as they are the key elements in enabling tools for renewable energy and hydrogen storage as well as indicator applications. Materials based on graphene have been shown to be very promising in achieving this goal due to their interesting properties, resulting in the conduction of a large number of theoretical and experimental studies [3]. With graphene being a flat monolayer of hexagonally arranged sp 2 -bonded carbon atoms bundled in a 2D figure-like field and highlight the advantages of using noble metal nanostructures in catalytic applications. This new information comes in addition to works from the literature that focus on biomedical applications or biosensors [17], diagnosis or therapy [18] and less in fields such as fuel cell technologies, renewable energy and hydrogen storage [19,20]. Thus, Section 2 will address the theme "Methods of Synthesis NPs@GO Nanocomposites", followed by Section 3 with examples of catalyst applications "Advantages and disadvantages of the synthesis methods of noble metals functionalized on graphene oxide" and ending with Section 4, "Conclusions".

Methods of Synthesis NPs@GO Nanocomposites
The last allotropic form of carbon graphene has demonstrated that it possesses remarkable physicochemical properties (specific surface area between 1500-2600 m 2 g −1 ) [21,22] that can be exploited for many electrochemical applications. Graphene possesses a single layer as a carbon sheet with the thickness of an atom. Graphene oxide (GO) represents the oxidized form of graphene and is considered in recent years as a suitable raw material for the manufacture of graphene. The most used method for obtaining graphene oxide, starting from graphite, is the Hummer chemical oxidation method. This method is shown schematically in Figure 1. This technique was also modified by other researchers in order to obtain an improved quality of graphene oxide. The obtained graphene oxide is subsequently dried and reduced using different reducing agents to improve electrical conductivity. To reduce graphene oxide, different reductants can be used (hydroiodic acid, hydrazine hydrate, hydrobromic acid, sodium borohydride, hydrochloric acid, sulfuric acid, ascorbic acid and dextrose) in order to eliminate the oxygen functional groups for the considerable improvement of electrical conductivity. The presence of different functional groups in graphene oxide influences the hydrophilic behavior, which is due to the level of oxidation. In addition, the multiple layers of GO are the consequence of a strong electrostatic charge but also of hydrophilicity, which can facilitate a good dispersion for anchored metals. The reduction in GO (specific surface area around 380-1000 m 2 g −1 , peak at 2θ = 11.2 • ) [21] is a classical method for obtaining a graphene-like structure. Reduced graphene oxide can be obtained by different chemical, thermal or photo-thermal reduction methods. Depending on the methods used, the produced rGO (specific surface area between 389.9-670 m 2 g −1 , peak at 2θ = 25.8 • , electrical conductivity: 103.3 S·cm −1 and I D /I G = 0.2) [23] approaches more or less close to the pure graphene structure. Among the reducing agents we mention inorganic chemical agents (for example, sodium borohydride) or organic (for example, phenyl hydrazine hydrate or hydroxylamine). Thermal reduction usually takes place in an inert atmosphere at elevated temperatures. This work aims to update new synthesis methods of graphene functionalized with noble metals (Pt, Au, Ag and Pd) and to introduce new catalysts in fuel cell applications and renewable technologies. The paper undertakes an analysis of the recent research in the field and highlight the advantages of using noble metal nanostructures in catalytic applications. This new information comes in addition to works from the literature that focus on biomedical applications or biosensors [17], diagnosis or therapy [18] and less in fields such as fuel cell technologies, renewable energy and hydrogen storage [19,20]. Thus, Section 2 will address the theme "Methods of Synthesis NPs@GO Nanocomposites", followed by Section 3 with examples of catalyst applications " Advantages and disadvantages of the synthesis methods of noble metals functionalized on graphene oxide " and ending with Section 4, "Conclusions".

Methods of Synthesis NPs@GO Nanocomposites
The last allotropic form of carbon graphene has demonstrated that it possesses remarkable physicochemical properties (specific surface area between 1500-2600 m 2 g −1 ) [21,22] that can be exploited for many electrochemical applications. Graphene possesses a single layer as a carbon sheet with the thickness of an atom. Graphene oxide (GO) represents the oxidized form of graphene and is considered in recent years as a suitable raw material for the manufacture of graphene. The most used method for obtaining graphene oxide, starting from graphite, is the Hummer chemical oxidation method. This method is shown schematically in Figure 1. This technique was also modified by other researchers in order to obtain an improved quality of graphene oxide. The obtained graphene oxide is subsequently dried and reduced using different reducing agents to improve electrical conductivity. To reduce graphene oxide, different reductants can be used (hydroiodic acid, hydrazine hydrate, hydrobromic acid, sodium borohydride, hydrochloric acid, sulfuric acid, ascorbic acid and dextrose) in order to eliminate the oxygen functional groups for the considerable improvement of electrical conductivity. The presence of different functional groups in graphene oxide influences the hydrophilic behavior, which is due to the level of oxidation. In addition, the multiple layers of GO are the consequence of a strong electrostatic charge but also of hydrophilicity, which can facilitate a good dispersion for anchored metals. The reduction in GO (specific surface area around 380-1000 m 2 g −1 , peak at 2θ = 11.2°) [21] is a classical method for obtaining a graphene-like structure. Reduced graphene oxide can be obtained by different chemical, thermal or photo-thermal reduction methods. Depending on the methods used, the produced rGO (specific surface area between 389.9-670 m 2 g −1 , peak at 2θ = 25.8°, electrical conductivity: 103.3 S·cm −1 and ID/IG = 0.2) [23] approaches more or less close to the pure graphene structure. Among the reducing agents we mention inorganic chemical agents (for example, sodium borohydride) or organic (for example, phenyl hydrazine hydrate or hydroxylamine). Thermal reduction usually takes place in an inert atmosphere at elevated temperatures.  In order for graphene to be electrochemically active, it is often used to modify the carbon structure by functionalizing it with different types of noble metal elements. This functionalization will be dealt with in this review. The reported methods aimed at the synthesizing of different metal nanoparticles (MNPs)/rGO nanocomposites involve chemical reduction, electrochemical deposition, thermally assisted method, photochemical reduction, microwave irradiation and sonochemical reduction. In most of these methods, a suspension of GO based on water or ethanol is allowed to react with a metal precursor in the presence of a reducing agent such as hydrazine hydrate, ascorbic acid, sodium citrate or glucose in order to obtain a simultaneous reduction in both the metal ions and the GO resulting in the production of MNPs/rGO composites.

Chemical Reduction
Chemical reduction is the most commonly used method to effectively immobilize NPs on GO and rGO. This method involves noble metal ions in solution being reduced to NPs on GO nanowires through additional reductants such as NaBH 4 , ascorbic acid, sodium citrate or hydrazine ( Figure 2). Usually, the GO and rGO dispersion is firstly mixed with noble metal salt solutions, following which the noble metal ions begin adsorbing on the GO and rGO nanosheet surface through electrostatic interaction. Following this, the reducing agents in the mixture reduce the noble metal ions adsorbed in NPs on GO and rGO nanowires [24]. In order for graphene to be electrochemically active, it is often used to modify the carbon structure by functionalizing it with different types of noble metal elements. This functionalization will be dealt with in this review.
The reported methods aimed at the synthesizing of different metal nanoparticles (MNPs)/rGO nanocomposites involve chemical reduction, electrochemical deposition, thermally assisted method, photochemical reduction, microwave irradiation and sonochemical reduction. In most of these methods, a suspension of GO based on water or ethanol is allowed to react with a metal precursor in the presence of a reducing agent such as hydrazine hydrate, ascorbic acid, sodium citrate or glucose in order to obtain a simultaneous reduction in both the metal ions and the GO resulting in the production of MNPs/rGO composites.

Chemical Reduction
Chemical reduction is the most commonly used method to effectively immobilize NPs on GO and rGO. This method involves noble metal ions in solution being reduced to NPs on GO nanowires through additional reductants such as NaBH4, ascorbic acid, sodium citrate or hydrazine ( Figure 2). Usually, the GO and rGO dispersion is firstly mixed with noble metal salt solutions, following which the noble metal ions begin adsorbing on the GO and rGO nanosheet surface through electrostatic interaction. Following this, the reducing agents in the mixture reduce the noble metal ions adsorbed in NPs on GO and rGO nanowires [24]. The three fundamental steps constituting the reduction process are as follows: (1) adsorption/reduction, (2) nucleation and (3) growth. The presence of oxygen-containing functional groups on the surface of the GO and rGO favors the adsorption of free metal ions through electrostatic interactions, followed by the reduction in metal ions by a reducing agent and finally the growth of NPs on the GO and rGO sheets. In spite of the formation of MNPs by chemical reduction being a facile process, this technique is limited due to difficulties sterned from size and morphology of the NPs, which can potentially result in polydisperse and large sizes of on GO and rGO surfaces [18].
Guo et al. [24], through the use of the chemical co-reduction method, synthesized a series of Pt-Ni/rGO catalysts with different Pt/Ni molar ratios and a total metal concentration of 0.99 mM. The production of these catalysts was performed through the rapid injection of KBH4 to reduce H2 PtCl6 and Ni(NO3)2 in the experiment at a temperature of 273 K and in an N2 atmosphere. X-ray powder diffraction (XRD) was used for the characterization of the detailed crystalline phases of the Pt-based NPs loaded on partially reduced The three fundamental steps constituting the reduction process are as follows: (1) adsorption/reduction, (2) nucleation and (3) growth. The presence of oxygen-containing functional groups on the surface of the GO and rGO favors the adsorption of free metal ions through electrostatic interactions, followed by the reduction in metal ions by a reducing agent and finally the growth of NPs on the GO and rGO sheets. In spite of the formation of MNPs by chemical reduction being a facile process, this technique is limited due to difficulties sterned from size and morphology of the NPs, which can potentially result in polydisperse and large sizes of on GO and rGO surfaces [18].
Guo et al. [24], through the use of the chemical co-reduction method, synthesized a series of Pt-Ni/rGO catalysts with different Pt/Ni molar ratios and a total metal concentration of 0.99 mM. The production of these catalysts was performed through the rapid injection of KBH 4 to reduce H 2 PtCl 6 and Ni(NO 3 ) 2 in the experiment at a temperature of 273 K and in an N 2 atmosphere. X-ray powder diffraction (XRD) was used for the characterization of the detailed crystalline phases of the Pt-based NPs loaded on partially reduced GOs. The XRD results for the Pt/rGO catalyst displayed four diffraction peaks of (111), (200), (220) and (311). The peaks seen in the Pt 40 -Ni 60 /rGO catalyst model were shifted to a high angle range suggesting the formation of ally structured Pt-Ni BNPs loaded on rGO. Transmission electron microscope (TEM) images clearly visualized the uniform distribution of the Pt and Pt-Ni NPs on the rGO with an average size of about 3.4 and 2.6 nm; these results were consistent with the ones from the Scherrer formula. This indicates that the size of the Pt 40 -Ni 60 BNPs of Pt 40 -Ni 60 /rGO catalyst could be reduced through the doping of Ni. Furthermore, the lattice stripe spacing of 0.220 nm can be assigned to the (111) lattice planes of Pt. The HRTEM image of Pt 40 -Ni 60 BNPs showed a lattice stripe spacing of 0.206 nm, value which is intermediary between the lattice spacing of crystalline Pt (111) at 0.226 nm and Ni (111) at 0.203 nm. This serves as a further indicator that the rGO-supported Pt-Ni BNPs possess an alloy structure. Moreover, elemental mapping images of the catalyst revealed that the C and O elements were uniformly distributed in the entire sample, and that Pt and Ni elements were aggregated into particles, thus serving as confirmation of the formation of alloy-structured Pt-Ni BNPs. After an XPS characterization of the Pt/rGO catalyst, the C 1s spectrum typically showed four peaks at 284.75, 284.86, 286.9 and at 287.6 eV, which assigned the characteristics of C-C, C=C, C-O and C=O, respectively. The fact that O 1s XPS spectrum can be deconvoluted into peaks corresponding to O=C (at 531.7 eV) and O-C (at 532.88 eV) can be used as an explanation for the incomplete reduction in the function groups (hydroxyl, carboxyl, etc.) of GO during the co-reduction process. Pairing peaks assigned to metallic Pt 0 4f( 7/2 ) and Pt 0 4f( 5/2 ) were located at 71.32 and 72.2 eV in the Pt 4f spectrum with one other pairing peak assigned to oxidized Pt (2+) 4f( 7/2 )and Pt (2+) 4f (5/2), being located at 72.2 and 75.62 eV, respectively. The first pairing peaks in the Pt/rGO catalyst were found to have higher binding energies than the bulk Pt 4f (7/2) and Pt 4f (5/2) (71.1 eV and 74.4 eV, respectively) by approximately 0.22 eV and 0.1 eV, which is an indicator that the Pt NPs were positively charged.
In another study [25], cobalt was used in the fabrication of AgPdNPs supported on rGO. Firstly, NaBH 4 was used to reduce Pd (2+) and Co (2+) with the resulting amorphous Co 3 (BO 3 ) 2 and AgPd on the surface of the rGO. The amorphous Co 3 (BO 3 ) 2 can be removed simply through etching with H 3 PO 4 . Using this method, the prevention of the aggregation of AgPd nanoparticles is effective, thus obtaining well-dispersed AgPd nanoparticles. The rGO catalyst supported by the AgPd nanoparticles was used for the catalytic transfer hydrogenation of nitro-compounds at room temperature using H-COOH as hydrogen donor. This obtained catalyst has a high catalytic efficiency, which is a result of the highly dispersed bimetallic nanoparticles coupled with the synergistic interaction between the metallic nanoparticles and the support. TEM showed that the AgPd particles of Ag 0.1 Pd 0.9 /rGO catalyst were effectively dispersed on the rGO lamellar support. The obvious lattice fringe found in the representative high-resolution TEM image of Co 6 Ag 0.1 Pd 0.9 /rGO demonstrated the good crystallinity of the AgPdNPs. It resulted in a lattice spacing of 0.23 nm, value between the (111) lattice spacing of face-centered cubic Ag at 0.24 nm and Pd at 0.22 nm. This implies that AgPd has formed as an alloy structure. It was found that the form of the AgPd nanoparticles was not uniform; however, there was a narrow size distribution averaging at 4.3 nm ± 0.9 nm. The XRD patterns of AgPd hybrids in Co 6 Ag 0.1 Pd 0.9 /rGO catalysts observe a diffraction peak located between the Ag (111, 2 theta = 38.03 deg) and Pd (111, 2 theta = 40.10 deg) diffraction peaks, further suggesting the formation of the AgPd alloy. As AgPd has been incorporated by Co 3 (BO 3 ) 2 , no AgPd peak of Co 6 Ag 0.1 Pd 0.9 /rGO could be observed, which is further attested by the TEM results. A nitrogen adsorption/desorption analysis was carried out at 77 K in order to determine the porosity of Ag 0.1 Pd 0.9 /rGO and Co 6 Ag 0.1 Pd 0.9 /rGO. Co 6 Ag 0.1 Pd 0.9 /rGO was found to have a low specific surface area of approximately 6 m 2 g −1 , which was attributed to the high amount of Co 3 (BO 3 ) 2 occupying the surface of the rGO. By comparison, in Co 6 Ag 0.1 Pd 0.9 /rGO, an increased absorption of nitrogen (310 m 2 g −1 ) can be observed. After removing Co 3 (BO 3 ) 2 by etching with H 3 PO 4 , (Co 6 )Ag 0.1 Pd. 0.9 /rGO results in high porosity, which serves in facilitating reactant diffusion to the metal nanoparticles. (Co 6 )Ag 0.1 Pd 0.9 /rGO presents a higher surface area (278 m 2 g −1 ) than Ag 0.1 Pd 0.9 /rGO (135 m 2 g −1 ). XPS measurement results showed that Ag and Pd alike in the (Co 6 )Ag 0.1 Pd. 0.9 /rGO catalyst are found in reduced states. The electronic states of Pd 0 , 3d5/2 and 3d3/2 can be detected at 335.83 eV and 341.11 eV, respectively. The spectra of the Ag 3d and Pd 3d observed attest that (Co 6 )Ag 0.1 Pd 0.9 /rGO is made of metallic Ag and Pd, serving as additional confirmation of the effective synthesis of the AgPd alloy. Pd 2+ peaks were detected at 338.14 eV and 343.48 eV, which can be attributed to the oxidation of metallic Pd in an environment containing oxygen.
Abbasi and co-workers [26] synthesized Pd nanoparticles using PdCl 2 and NaBH 4 as a strong reducing agent and polyvinyl alcohol (PVA) as stabilizing agent. During the chemical process, the palladium Pd 2+ from the salt solution was reduced to Pd • as nanoparticles. A total of 120 mL of distilled water, 0.88 mL of freshly prepared 2% polyvinyl alcohol (PVA) solution and 2.15 mL of 0.02 M PdCl 2 solution were immediately added, resulting in a yellow-brown solution. A 0.1 M NaBH 4 solution (0.86 mL) was then slowly added to the reaction mixture while stirring vigorously. Observing an immediate color change to brown served as an indicator for the formation of Pd NPs. Following UV-Vis spectroscopic analysis, the palladium nanoparticles present the absorption spectrum of 4.1 p.m. It was found that the absorption peak of the Pd 2+ precursor no longer appears at 420 nm, with this peak disappearing being an indicator for the complete reduction in the Pd 2+ nanoparticles to Pd • . After three measurements, a size of 122 nm was found. The zeta potential of the palladium nanoparticles was immediately at −3.91 ± 3.85 mV, as shown. Regarding the stability of Pd NPs, although the zeta potential showed lower values, the synthesized nanoparticles were stable at room temperature and did not show any sign of agglomeration during the last 12 months.
Shu et al. [27] used a mildly tempered process of oxidation to obtain the in situ oxidation of PdIr alloy on NGs (nitrogen-doped graphene), (PdIrO/NGs). K 2 PdCI 4 (36.6 mg) and H 2 IrCl 6 ·6H 2 O (7.7 mg) were dispersed in deionized water and then mixed under strong stirring. The obtained solution was added to the NGs dispersion with stirring, and then the NaBH 4 mixture was slowly dispersed into the aqueous solution. The obtained dispersion reacted in an ice bath under an N 2 atmosphere for 300 min. The powder resulting from vacuum filtration, washing and lyophilization was calcined at 250 • C to obtain PdIrO/NGs. The same steps excluding calcination were used to synthesize the PdIrO/NGs catalyst. The XRD patterns of PdIrO/NGs, PdIr/NGs and Pd/NGs showed a broad peak between 20 • and 30 • , which was identifiable as the proprietary peak of NGs. The two diffraction peaks of 39.4 • and 45.8 • for Pd/NGs were found to correspond to the (111) and (200) planes of metallic Pd, respectively. The pattern revealed through XRD of PdIrO/NGs, which evidently showed a positive shift of the diffraction peak between 39.4 • and 40.7 • in comparison to the peak of Pd/NGS, it was an indicator of the high formation quality of the Pd-Ir alloy. In addition, in the XRD pattern of PdIrO/NG S , three diffraction peaks can be clearly observed at 33.9 • , 41.9 • and 54.8 • , which correlate to the (101), (110) and (112) planes of PdO. Following the XPS analysis, a deconvolution of the Pd 3d spectra was discovered into two groups at 340.6 eV 335.3 eV, whereas the peaks discovered at 342.4 eV and 336.9 eV in the spectra may relate to PdO/ 2/2 and Pd 3d 5/2 . A significant increase in the concentration of PdO and IrO 2 in PdIrO/NG S can be observed, meaning that the alloy was oxidized. TEM analysis showed a uniform monodispersion of the nanoparticles on the NGS surface with a slight decrease in particle size observed after alloy formation and with a significant increase following calcination. EDS mapping demonstrated the homogeneous dispersion of C, N, O, Pd and Ir in PdIrO/NG S . BET (Brunauer-Emmett-Teller type IV) isotherms indicated that additional mesopores can be obtained in PdIrO/NG S , as they are in agreement with the pore dimension distribution curves. The largest specific surface area is that of PdIrO/NG S , with a higher limit of 122.4 m 2 g −1 while PdIrO/NG S, with a value of 96.9 m 2 g −1 and with a value of 40.9 m 2 g −1 , have lower surface areas. This demonstrates that large BET surfaces and meso-porous structure are used to improve electrocatalytic activity.
Teffu et al. [28] synthesized Pd-rGO using electroless palladium deposition by immersing the rGO in a sodium hypophosphite-based plating bath. The electroless plating bath, which contained 50 mL of sodium hypophosphite (10 g L −1 ) as reducing agent and 5 g of rGO, was subjected to constant stirring (300 rpm) for 30 min at 50 • C, followed by adding PdCl 2 , 160 mL of NH 4 OH (28%) and 27 g of NH 4 Cl, respectively. A total of 50 mL of plating solution was added to the bath solution and the mixture was stirred for 30 min to allow Pd plating on the surface of the rGO sheets. The mixture was filtered, washed with ultrapure water and dried overnight at 80 • C. As observed from the XRD patterns in the case of Pd-rGO, the characteristic peak at 2θ = 24 • is attributed to the (002) planes of the chemically reduced GO stack, which is an indicator for the effective reduction in GO by hydrazine hydrate. At the same time, it was found that the two diffraction peaks centered at 2θ of 39 and 45 • can be attributed to the (111) and (200) reflections of the Pd nanoparticles, respectively. Investigation on the thermal stability of the fabricated Pd-rGO nanocomposite was performed using thermogravimetric analysis (TGA), with the results concluding that Pd-rGO shows a 15% loss of weight for the entire investigated temperature range (up to 560 • C). At 100 • C, the slight lost weight was caused by the loss of adsorbed water, while the losses of up to 400 • C are a result of the decomposition of residual hydroxyl and carboxyl functional groups. The FTIR spectra of Pd-rGO nanocomposite showed, as is expected, either the disappearance or the significantly reduced intensity of the FTIR peaks belonging to rGO after the reduction process, which serves as confirmation of the formation of Pd nanoparticles on rGO. Further observation showed very low band intensities in Pd-rGO, with some even disappearing, with reference to the rGO spectrum. This implied that the palladium incorporation on the rGO is on the surface of the graphene oxide sheets.
Rajkumar et al. synthesized [29] NP Au@Pt by two chemical methods. Au@Pt NPs were initially synthesized using Fren's method: HAuCl 4 was placed in a triple-neck flask connected to a condenser under strong stirring. This was heated to a boil, following which a solution of sodium citrate was quickly inserted and then the mixture was brought to a boiling temperature again. The boiling process was maintained for 10 min, with stirring being maintained for an additional 15 min post removal of the heat source. This solution was then naturally cooled to room temperature. Seed-mediated growth was the second method used to synthesize Au@Pt NPs. H 2 PtCl 6 , deionized water and prepared Au-NPs were mixed in a beaker. This obtained mixture was refrigerated afterward to 4 • C followed by slowly adding NaBH 4 under stirring to obtain Au@Pt NPs. The nanostructures and morphology of multi-walled carbon nanotubes (MWCNTs) and GO/MWCNT dispersion were conducted by TEM and showed interlaced tubular structures with an average diameter of approx. 20 nm. Several lamellar structures integrated with carbon nanotubes (CNTs) could be observed upon the supplementation of GO, essentially scattering the CNTs. The Au-NPs showed a typical spherical structure with a particle diameter of approximately 13 nm. The reduction by hydroxyl groups of chloruretic ions on sodium citrate resulted in the formation of Au NPs. Synthesizing Au@Pt NPs resulted in a slightly increased particle size while for GO/MWCNT/Au@Pt NPs, the successive drop method was employed in the copper mesh. Au@Pt NPs were pre-applied on the GO/MWCNT surface, thus a new three-dimensional sensing interface for glucose sensing was constructed. Spectra

Thermally Assisted Method
The thermally assisted method is one of the important methods used to fabricate NPs@GO nanocomposites more simply at high temperature ( Figure 3) [13]. Thermally assisted synthesis is an easy and efficient method used to immobilize NPs on GO. The speed of the process makes the size and the distribution of the NPs@GO, in this case, difficult to control.

Thermally Assisted Method
The thermally assisted method is one of the important methods used to fabricate NPs@GO nanocomposites more simply at high temperature ( Figure 3) [13]. Thermally assisted synthesis is an easy and efficient method used to immobilize NPs on GO. The speed of the process makes the size and the distribution of the NPs@GO, in this case, difficult to control. Abdulhusain et al. [30] prepared Ag-ZnO-rGO ternary nanocomposites by an in situ hydrothermal process in the presence of 1,8-diamino-3,6-dioxaoctane (DDO). The nanophotocatalysts possessing attractive physicochemical properties led to the idea of using a different procedure for the enhancement of Ag-ZnO-rGO nanocomposite properties in applications related to water treatment. Preparation of the appropriate nanocomposites at a lower temperature and for a shorter time have led to in situ synthesis being the chosen method. A 1,8-diamino-3,6-dioxaoctan was utilized in the synthesizing of the ternary Ag-ZnO-rGO nanocomposites, since the generous DDO carbon chain acts as a limiting factor to the accumulation of nanostructures. Firstly, graphene oxide was dispersed in distilled water resulting in solution A. Following this, zinc nitrate hexahydrate was in an aqueous mixture containing DDO, which resulted in solution B. The next step was the preparation of the silver nitrate aqueous solution. Finally, solutions A and B were mixed, while also pouring ethanol into the mixture. The resulting transparent suspension was placed in an autoclave and conditioned at 140 °C for an interval of 120 min. The collected precipitate was washed several times with distilled water and ethanol before being dried. The percentage weight of Ag was adjusted in order to attain the product with the highest performance. Moreover, studies were conducted on the effect of 1, 8-diamino-3, 6-dioxaoctan on the size distribution, morphology and purity of the product. Finally, the nanocomposite was exposed to degradation using a pollutant (RhB-rhodamine-B) in order to study its photocatalytic activity. Studies were performed to evaluate the changes in photocatalytic performance of the product by varying the pH and the concentration of Ag and the dye itself, respectively. The largest percentage of dye degradation was observed at a concentration of 10 ppm, with the pH of the mixture regulated to 11. The increased performance of the photocatalyst in alkaline media can be attributed to absorbed hydroxyl anions at the surface of the photocatalyst. Based on kinetic studies, photocatalytic reactions follow pseudo-first order with holes and hydroxyl radicals being critical active agents for photocatalysis. It is worth noting that the used synthesis process for this type of nanocomposite can be further applied for the rest of the nanocomposites due to its simplicity and ecofriendliness.
Rudra et al. used the thermally assisted method in synthesizing Au-Mn3O4-decorated graphene oxide and Au-Mn3O4 nanocomposite [31]. It was synthesized as follows: GO was added to distilled water in a beaker and sonicated for 30 min and this solution was Abdulhusain et al. [30] prepared Ag-ZnO-rGO ternary nanocomposites by an in situ hydrothermal process in the presence of 1,8-diamino-3,6-dioxaoctane (DDO). The nanophotocatalysts possessing attractive physicochemical properties led to the idea of using a different procedure for the enhancement of Ag-ZnO-rGO nanocomposite properties in applications related to water treatment. Preparation of the appropriate nanocomposites at a lower temperature and for a shorter time have led to in situ synthesis being the chosen method. A 1,8-diamino-3,6-dioxaoctan was utilized in the synthesizing of the ternary Ag-ZnO-rGO nanocomposites, since the generous DDO carbon chain acts as a limiting factor to the accumulation of nanostructures. Firstly, graphene oxide was dispersed in distilled water resulting in solution A. Following this, zinc nitrate hexahydrate was in an aqueous mixture containing DDO, which resulted in solution B. The next step was the preparation of the silver nitrate aqueous solution. Finally, solutions A and B were mixed, while also pouring ethanol into the mixture. The resulting transparent suspension was placed in an autoclave and conditioned at 140 • C for an interval of 120 min. The collected precipitate was washed several times with distilled water and ethanol before being dried. The percentage weight of Ag was adjusted in order to attain the product with the highest performance. Moreover, studies were conducted on the effect of 1, 8-diamino-3, 6-dioxaoctan on the size distribution, morphology and purity of the product. Finally, the nanocomposite was exposed to degradation using a pollutant (RhB-rhodamine-B) in order to study its photocatalytic activity. Studies were performed to evaluate the changes in photocatalytic performance of the product by varying the pH and the concentration of Ag and the dye itself, respectively. The largest percentage of dye degradation was observed at a concentration of 10 ppm, with the pH of the mixture regulated to 11. The increased performance of the photocatalyst in alkaline media can be attributed to absorbed hydroxyl anions at the surface of the photocatalyst. Based on kinetic studies, photocatalytic reactions follow pseudo-first order with holes and hydroxyl radicals being critical active agents for photocatalysis. It is worth noting that the used synthesis process for this type of nanocomposite can be further applied for the rest of the nanocomposites due to its simplicity and eco-friendliness.
Rudra et al. used the thermally assisted method in synthesizing Au-Mn 3 O 4 -decorated graphene oxide and Au-Mn 3 O 4 nanocomposite [31]. It was synthesized as follows: GO was added to distilled water in a beaker and sonicated for 30 min and this solution was then placed into screw cap tubes. Afterward, manganese acetate was added to the reaction mixture and the gold (III) solution. In order to balance the pH, sodium acetate was added to the solution. Wang et al. presented the preparation of Ag/CeO 2 anchored on reduced graphene oxide (rGO) nanocomposite. Ag/CeO 2 -rGO is considered to be a simple, recyclable and sustainable photocatalyst for the esterification of aldehydes at room temperature under visible light irritation [15]. The catalyst was prepared as follows: 5 mmol of Ce(NO 3 ) 3 ·6H 2 O and 0.5 mmol of AgNO 3 were slowly added to 1.8 mg mL −1 GO aqueous solution with constant stirring and followed by the addition of 0.5 mmol polyethylene glycol molecular weight 4000 (PEG 4000) and 20 mmol urea. The reaction mixture was transferred to an autoclave for the hydrothermal reaction at 185 • C for about 24 h. After cooling in the autoclave, the obtained solid sample was washed with deionized water and ethanol, then dehydrated at 50 • C in a hot air oven for 12 h. XRD analysis showed two additional peaks at 25.5 and 38.19 degrees, corresponding to the (002) plane of rGO and (111) planes with metallic phases of Ag. The specific surface area of reduced graphene oxide-embedded Ag/CeO 2 was found to be 292.6 m 2 /g with a maximum of the pores in ranges from 5 to 15 nm.
Das et al. synthesized using thermally assisted method Pt-M/GNPs (graphene nanoplatelets) (M = Ni, Fe and Cu) of catalysts. The adsorption isotherm showed that the use of 0.2 g of metal precursor over 0.1 g of GNPs yielded the highest metal loading [1]. Pt-M/GNPs catalysts were characterized from a physical point of view using XRD analysis, thermogravimetric analysis (TGA), inductively coupled plasma mass spectrometry analysis (ICP-MS), high resolution transmission electron microscopy analysis (HRTEM) and Raman analysis. XRD was used on the synthesized catalyst samples to determine the development of metal crystal structures on the GNPs support. The samples were scanned between 10 • < 2θ < 90 • . The distinct diffraction for the Pt/GNP catalyst corresponds to the (111), (200), (220) and (311) planes of Pt in the face-centered cubic crystal structure. TGA analyses were carried out between at a temperature ranging from 25 to 1000 • C with a 10 • C min −1 heating rate under air atmosphere. TGAs were used on the GNPs support material in order to determine the total metal loading. The results showed that the weight content of the metal nanoparticles (Pt-Ni, Pt-Fe and Pt-Cu) were approximately 24.0-30.0 wt%. ICP-MS analysis was employed in order to establish the composition of the Pt-M/GNPs catalysts. The results showed that the Pt loading (% by weight) was between 17.5% and 25.4% and the metal loading (% by weight)was 3.40% Ni, 1.40% Fe and 3.20% Cu. The particle size and morphology were investigated using TEM, considering its capability for imaging at an atomic scale. The average particle size was found to be 1.7 nm for Pt-Ni/GNPs, 1.6 nm for Pt-Fe/GNPs and 2.1 nm for Pt-Cu/GNPs. Raman spectroscopy was used to find I D /I G , the ratio between the intensities of the D band and the G band, a measure commonly employed to characterize the defect concentration in samples of graphene. The I D /I G values of the Pt-Ni/GNPs, Pt-Fe/GNPs and Pt-Cu/GNPs catalysts were discovered to be 0.230, 0.340 and 0.470, respectively [1].
Xue et al. used the thermally assisted method to anchor Pt nanocrystals onto threedimensional (3D) porous boron and nitrogen double-doped reduced graphene oxidecarbon nanotube frameworks (Pt/BNrGO-CNT) [32]. They used the solvothermal method to obtain different BNrGO/CNT feeding ratios in the 3D Pt/BNrGO-CNT catalysts. To obtain this result, a mixture of CNT powder and GO solution NH 4 [BF 4 ] is reacted for 24 h at 180 • C inside a high-pressure reactor. Afterward, a formulated (BNrGO) 5 -(CNT) 5 support material is inserted into the ethylene-glycol mixture containing K 2 PtCl 4 , and additional processing at 120 • C is performed for a duration of 12 h in order to obtain the final product. Another ration of BNrGO-CNT was also prepared. The results obtained through ICP-MS determined the Pt loadings for the Pt/(BNrGO) 3 -(CNT) 7  Grad et al. prepared Pd/rGO and Pd-Au/rGO catalysts through wet impregnation of GO using an aqueous mixture of metal salts. The resulting mixture of GO and metal ions was then processed through thermal treatment in (H 2 + Ar) mixture [33]. The Pd/rGO catalyst was prepared using GO and PdCl 2 solution in diluted HCl by wet impregnation, resulting in 10 wt.% palladium on rGO. The target Pd-Au/rGO with metal concentrations of 7.5 wt.% Pd and 2.5 wt.% Au was obtained similarly through wet impregnation, employing a mixture comprising PdCl 2 and HAuCl 4 aqueous solutions. In both cases, the impregnated samples were dried at ambient temperature followed by thermal reduction in Ar. Afterward, it was thermal treated in a (H 2 + Ar) mixture (10 vol.% H 2 ) for 30 min at 250 • C. The resulting surface areas determined using the BET method are 210 m 2 /g for Pd/rGO and 206 m 2 /g for Pd-Au/rGO. The XRD profiles for both of the catalysts display the (002) graphene reflexion situated at 23 • for Pd/rGO and at 23.7 • for the Pd-Au bimetallic catalyst, as well as the metal reflexions: Pd (111) at 39.9 • , Pd (200) at 46.4 • for Pd/rGO and one metal reflexion situated at 38.9 • for Pd-Au/rGO. Size of the metal crystallite calculated by XRD is 5 nm for Pd/rGO and 3.5 nm for Pd-Au/rGO. The bimetallic catalyst displays a distance between the carbon layers of 0.378 nm, whereas the Pd/rGO catalyst displays a distance of 0.386 nm, with the medium number of graphene layers for Pd/rGO being 4 and for Pd-Au/rGO being 5.5. The burning temperature for the palladium containing catalyst is 517 • C, while the Pd-Au bimetallic has a much lower value at 447 • C. The I D /I G intensity ratio of the D and G bands is 0.90 for Pd/rGO and 0.85 for Pd-Au/rGO; values were obtained from Raman spectra [33].

Microwave Irradiation Method
In recent years, microwave irradiation has been used as an eco-friendly method in the synthesizing organic, inorganic and inorganic-organic hybrid materials due to its well-known advantages over conventional synthetic methods. The size as well as distribution of NPs synthesized using the light or microwave irradiation method could be easily controlled compared to reductant-assisted or thermal-assisted reduction method, by changing the intensity, power and irradiation time of the light or microwave (Figure 4). Another important property of microwave irradiation synthesis is that along with the reduction in metals, simultaneous reduction in graphene oxide is possible [13].
Wojnicki et al. synthesized Au/rGO. They first dissolved metallic gold in aqua regia to obtain the Au(III) chloride complex [34]. A Magnum II (Ertec, Poland) 600 W microwaveheated digestion system was used to obtain Au/rGO. The parameters of the microwaveheated digestion system were set to a temperature of 523 K using microwaves at a frequency of 2.45 GHz for 10 min. The pressure in the reaction vessel increased from atmospheric to approximately 40 bar. XRD showed that the intensity of diffraction lines ascribed to GO (001) and graphite (002) crystal planes was much smaller when compared to the intensity of Au (111) line. The average value of the AuNPs diameter was calculated at 12 nm. The high-resolution Au spectrum confirmed the presence of metallic gold by XPS. XPS peaks were ascribed to Au 4 f 7/2 with a binding energy 84 eV and spin-orbit energy shift of 3.7 eV. The ratio of the intensities of the D and G bands (I D /I G ) presented by the Raman spectra of the investigated samples proved to be equal to 0.60 for GO, 0.63 for rGO and 0.81 for Au/rGO, respectively. The obtained I D /I G values are directly proportional with the number of structural defects in the sample. Wojnicki et al. synthesized Au/rGO. They first dissolved metallic gold in aqua regia to obtain the Au(III) chloride complex [34]. A Magnum II (Ertec, Poland) 600 W microwave-heated digestion system was used to obtain Au/rGO. The parameters of the microwave-heated digestion system were set to a temperature of 523 K using microwaves at a frequency of 2.45 GHz for 10 min. The pressure in the reaction vessel increased from atmospheric to approximately 40 bar. XRD showed that the intensity of diffraction lines ascribed to GO (001) and graphite (002) crystal planes was much smaller when compared to the intensity of Au (111) line. The average value of the AuNPs diameter was calculated at 12 nm. The high-resolution Au spectrum confirmed the presence of metallic gold by XPS. XPS peaks were ascribed to Au 4 f7/2 with a binding energy 84 eV and spin-orbit energy shift of 3.7 eV. The ratio of the intensities of the D and G bands (ID/IG) presented by the Raman spectra of the investigated samples proved to be equal to 0.60 for GO, 0.63 for rGO and 0.81 for Au/rGO, respectively. The obtained ID/IG values are directly proportional with the number of structural defects in the sample.
Gold nanoparticles decorated on rGO were prepared using the microwave-assisted process (MW). The procedure has demonstrated remarkable advantages as eco-friendly method for Au/rGOs obtaining with simultaneous reduction in graphene oxide and formation of gold nanoparticles by an innovative one-step process. The characterization of prepared samples demonstrated good chemical stability and controllable morphology. The samples were used for membrane electrode assembly development and tested in operation of proton exchange membrane fuel cells. The electrochemical stability of the innovative Au/rGO-based cathode was analyzed using several accelerated stress tests (ASTs) by considering the cycling potential protocol. The electrochemical analysis considering the I-V study, cyclic and linear voltammetry has provided improved performances in comparison with the standard commercial cathode. The aggressive AST indicated an excellent stability; thus, the authors reported an improved electrocatalyst for oxygen reduction reaction with higher stability and durability for fuel cells. Moreover, the paper indicates the possibility of extending the protocol using the microwave-assisted process for obtaining other noble metal nanoparticles supported on rGO [35][36][37][38][39].
A single-step route to obtain platinum/platinum-cobalt uniformly distributed nanoparticles supported on reduced graphene oxide was developed recently. This route provides significant advantages such as its low cost, low time-consuming nature and high yield in comparison to state-of-the-art chemical methods used to prepare efficient Pt/rGO catalyst. The morphology of prepared samples has been evaluated by specific techniques, while the electro catalytic durability has been evaluated using the electrochemical performances in fuel cells [40,41]. Significant performance and stability in PEM fuel cells was demonstrated. The produced Pt-rGO-based membrane electrode assemblies were studied for stability under fuel starvation in comparison with commercial Pt/C-based membrane electrode assemblies. The electro-chemical activity was studied and the electrochemical response indicated the higher stability during degradation test under fuel starvation in Gold nanoparticles decorated on rGO were prepared using the microwave-assisted process (MW). The procedure has demonstrated remarkable advantages as eco-friendly method for Au/rGOs obtaining with simultaneous reduction in graphene oxide and formation of gold nanoparticles by an innovative one-step process. The characterization of prepared samples demonstrated good chemical stability and controllable morphology. The samples were used for membrane electrode assembly development and tested in operation of proton exchange membrane fuel cells. The electrochemical stability of the innovative Au/rGO-based cathode was analyzed using several accelerated stress tests (ASTs) by considering the cycling potential protocol. The electrochemical analysis considering the I-V study, cyclic and linear voltammetry has provided improved performances in comparison with the standard commercial cathode. The aggressive AST indicated an excellent stability; thus, the authors reported an improved electrocatalyst for oxygen reduction reaction with higher stability and durability for fuel cells. Moreover, the paper indicates the possibility of extending the protocol using the microwave-assisted process for obtaining other noble metal nanoparticles supported on rGO [35][36][37][38][39].
A single-step route to obtain platinum/platinum-cobalt uniformly distributed nanoparticles supported on reduced graphene oxide was developed recently. This route provides significant advantages such as its low cost, low time-consuming nature and high yield in comparison to state-of-the-art chemical methods used to prepare efficient Pt/rGO catalyst. The morphology of prepared samples has been evaluated by specific techniques, while the electro catalytic durability has been evaluated using the electrochemical performances in fuel cells [40,41]. Significant performance and stability in PEM fuel cells was demonstrated. The produced Pt-rGO-based membrane electrode assemblies were studied for stability under fuel starvation in comparison with commercial Pt/C-based membrane electrode assemblies. The electro-chemical activity was studied and the electrochemical response indicated the higher stability during degradation test under fuel starvation in comparison with commercial Pt/C catalyst. These results extend the applicability of described preparation protocol to other noble/transition metal nanoparticles supported on graphene-based materials.

Ultrasonication Method
The ultrasonic method ( Figure 5) leads to the rapid heating of the liquid to temperatures of 5000 K in a few nanoseconds, resulting in microbubbles with an effective effect. These microbubbles act as chemical reactors. Oxidative and reducing radicals are generated in the cavitation effect during sonolysis. Sonication in the range of 20 to 1000 kHz leads to the formation of MNPs from metal precursor solution. The collapse of these microbubbles leads to the generation of high temperatures inside the bubbles [18]. Ultrasonic testing techniques are widely accepted for testing materials in many industries, including power generation, steel, aluminum, titanium production, airframe manufacturing, jet engine manufacturing and shipbuilding [42].

Ultrasonication Method
The ultrasonic method ( Figure 5) leads to the rapid heating of the liquid to temperatures of 5000 K in a few nanoseconds, resulting in microbubbles with an effective effect. These microbubbles act as chemical reactors. Oxidative and reducing radicals are generated in the cavitation effect during sonolysis. Sonication in the range of 20 to 1000 kHz leads to the formation of MNPs from metal precursor solution. The collapse of these microbubbles leads to the generation of high temperatures inside the bubbles [18]. Ultrasonic testing techniques are widely accepted for testing materials in many industries, including power generation, steel, aluminum, titanium production, airframe manufacturing, jet engine manufacturing and shipbuilding [42]. Li et al. synthesized the AuPs/rGO through a mixture of 4 mg/mL GO suspension and 0.48 mg/mL AuPs solution with a volume ratio of 1:1; it was then sonicated for 1 h. After the AuPs/rGO was reduced by hydroiodic acid, it was washed with deionized water and then dried in air. The images of AuPs/rGO composite by SEM showed the uniform distribution of the AuPs on the surface of rGO. XRD measurements and the corresponding calculated results are consistent with the SEM images. The AuPs composites are inserted into the layered graphene sheets. The diffraction peak is 2θ = 8.84° for rGO to 2θ = 7.86° for AuPs-rGO. XRD measurements are consistent with the SEM images. The Raman spectra of both the AuPs-rGO and pure rGO film show a wide band at 2400 cm −1~3 200 cm −1 [43].
Tran et al. prepared the Ag/GO nanocomposites through the ultrasonication method. Ag/GO nanocomposites were synthesized with GO, double-distilled water and sonicated for a duration of 10 min, after which AgNO3 was added. Centrifugation at 12,000 rpm was used to separate the final Ag/GO nanocomposites, which were then washed with doubledistilled water [44]. The FTIR spectrum of GO reveals several proprietary peaks situated at 3224, 1724, 1226 and 1050 cm −1 for hydroxyl -OH, carboxyl -COOH, epoxy C-O-C and alkoxyl C-O. After anchoring with AgNPs, the epoxy stretching mode at 1226 cm −1 is no longer present, while peaks that are indicative of different oxygen functional groups remain well-preserved. Nanocomposites of GO and Ag/GO reveal a diffraction peak at 2θ of 10.1° in the XRD patterns relating to the (002) crystal plane of GO nanosheets. In addition to the distinctive diffraction peak of GO, the Ag/GO nanocomposites also exhibit a number of separate peaks at 2θ of 38.1, 44.2, 64.5 and 77.5 degrees, which can be attributed to the (111), (200), (220) and (311) facets of typical fcc metallic Ag (JCPDS No. 04-0783), respectively. The patterns revealed by XRD demonstrate the effective adhesion of AgNPs to GO nanowires. The ID/IG ratio of the GO increased from 0.87 to 0.92 when the GO was anchored with AgNPs. The C/O atomic ratio found in the Ag/GO nanocomposites is Tran et al. prepared the Ag/GO nanocomposites through the ultrasonication method. Ag/GO nanocomposites were synthesized with GO, double-distilled water and sonicated for a duration of 10 min, after which AgNO 3 was added. Centrifugation at 12,000 rpm was used to separate the final Ag/GO nanocomposites, which were then washed with doubledistilled water [44]. The FTIR spectrum of GO reveals several proprietary peaks situated at 3224, 1724, 1226 and 1050 cm −1 for hydroxyl -OH, carboxyl -COOH, epoxy C-O-C and alkoxyl C-O. After anchoring with AgNPs, the epoxy stretching mode at 1226 cm −1 is no longer present, while peaks that are indicative of different oxygen functional groups remain well-preserved. Nanocomposites of GO and Ag/GO reveal a diffraction peak at 2θ of 10.1 • in the XRD patterns relating to the (002) crystal plane of GO nanosheets. In addition to the distinctive diffraction peak of GO, the Ag/GO nanocomposites also exhibit a number of separate peaks at 2θ of 38. Mehmandoust et al. prepared Pt/CQDs@rGO nanocomposite (CQDs-carbon quantum dots) by ultrasonication method [46]. The Pt/CQDs@rGO nanocomposite is prepared using the GO dispersion, aqueous sodium citrate and ammonia solution for the CQDs, following which H 2 PtCl 6 was added to the solution. In the XRD patterns, the characteristic peaks of (002) obtained at 11.0 • (d002 = 0.85 nm), 28.9 • and 24.0 • were for GO, CQDs and Pt/CQDs/rGO, respectively. After the reduction process, the diffraction peaks are observed at, respectively, 46. Mariappan et al. presented the study of Ag/rGO prepared with glucose, vitamin C and NaBH 4 as reducing agents through the ultrasonication method [47]. The Ag/rGO is prepared using GO, polyvinylpyrrolidone is dispersed in double-distilled water by continuous sonication for 2 h and afterward, AgNO 3 and glucose are added. The same experimental procedure is repeated for vitamin C and NaBH 4  Mao et al. [49] synthesized the graphene oxide sheets decorated by silver nanoparticles using the sonication method. This process used graphene oxide colloid, AgNO 3 and cetyl trimethylammonium bromide. The final product is graphene oxide sheets that are decorated by silver nanoparticles. The peaks at 38.31 • , 44.41 • , 63.51 • and 77.71 • can be assigned to the (111), (200), (220) and (311) crystalline planes of silver, respectively, which shows that the silver nanoparticles are composed of pure crystalline silver. The particle diameter of silver nanoparticles is about 10 nm. The band of silver nanoparticles is at about 414 nm.
For the preparation of graphene materials doped with metal nanomaterials, the synthesis methods are very important to ensure the best dispersion of the metal particles and the narrowest distribution of their size, because both significantly affect the electrocatalytic activity.
In Table 1 we presented the synthesis method according to the noble metals used. In conclusion, we can state that the chemical reduction method is specific to the noble metal Pd, the thermally assisted method is specific to the noble metals Au, Ag and Pt, the microwave-assisted method is specific to the noble metals Au and Pt and the ultrasonication method is specific to all four noble metals present in our study (Au, Ag, Pt and Pd). Table 1. Synthesis method depending on the nature of the introduced metal.

Advantages and Disadvantages of the Synthesis Methods of Noble Metals Functionalized on Graphene Oxide
In recent years, different methods have been proposed for the synthesis of nanoparticles deposited on a graphene support. The choice of the most suitable method has the greatest importance in terms of the structure and catalytic efficiency of the catalysts. Table 2 presents the advantages, disadvantages and applications of the most known methods used in the synthesis of nanoparticles deposited on a graphene support.

Thermally assited method
Possibility of variation of the electronic properties of the graphene oxide photoreduction composite; Photo-electrochemical reduction process is simple and also inexpensive; Increase in charge redox reaction and ion diffusion via photovoltaic effect.
o The level of reduction in certain groups on the surface of graphene oxide is not very relevant.

Pulsed laser ablation in liquids (PLAL)
Could provide a green synthesis strategy of GO metal nanocomposites; Short reaction time-from several hours to a few minutes; Does not involve toxic chemicals.
o Lack of optimized parameters of the PLAL method for improving the yield and desired properties of carbon nanomaterials; o The importance of the effect of the liquid carrier medium on the GO optical properties.
o High loss of mechanical integrity of freeze-dried nanosheets; o Presence of a quantity of metal impurities after reduction.

Electrochemical deposition
Simple, efficient and fast technique; Can control the size of noble metal nanoparticles and the deposition time.

Microwave-assisted synthesis
Uniform and fast heating technique; Uniform dispersion of a smallest particle size; High electrocatalytic activity of nanoparticles.
o Long and time-consuming to complete a reaction; o Process set up is difficult to realize.

Seed mediated growth method
Small-size nanoparticle synthesis; Well-controllable growth rate.
o Possible agglomeration and unreliable electrostatic attraction of metal precursors and GO.
o Linking agent is required, because the metal nanoparticle and graphene sheets are synthesized separately; o Aggregation of the metal nanoparticles before their attachment onto the GO can be a problem.
-Electron emission applications; -Electrochemistry applications; -Fuel cell applications. [78][79][80][81] In conclusion, the most valuable method among the preparation methods of graphenedeposited nanomaterial catalysts is microwave field irradiation, especially due to the short synthesis time, the fast and uniform heating and the significant challenge in controlling uniformity of the metal nanoparticle's decoration on the graphene surface. By applying irradiation in the microwave field, under the influence of temperature, homogeneous reaction centers are formed in the reaction medium at the interface between the irradiationsensitive graphene support and the metal precursor. Additionally, the presence of a reducing agent in the reaction medium means that the precursor can be converted to its metallic form by microwave irradiation.
The qualities of noble metals have demonstrated a special efficiency in the electrocatalytic activity and the electrochemical stability of compounds based on carbon and graphene oxide. In order to improve the oxygen reduction reaction (ORR) and the quality of hydrogen adsorption and desorption, a higher electrochemical active surface area (ECSA) of the catalyst based on noble metals is necessary. The intrinsic increase in the active surface is proportional to the metal content in the chemical compound and to the dispersion of metal nanoparticles on the rGO sheets. The uniform distribution and surface morphology of noble metal nanoparticles on rGO have an effect on the ORR. An excessive reaction energy can cause an agglomeration of the noble metal nanoparticles, leading to particle sizes over 10 nm and the suppression of catalytic activity by reducing the active surface. Figure 6 present the trend of noble metal nanocomposites synthesis methods in different applications. Thus, it can be seen that the most applications of graphene functionalized with noble metals are in applications with fuel cells, renewable energy sources (photovoltaics, production of green hydrogen) and supercapacitors.

Conclusions
This review presents the most used and up-to-date methods for the synthesis of graphene functionalized with noble metals (Pt, Ag, Pd and Au) as well as the relevant methods for the characterization of catalysts. The potential of capitalizing on the improved catalytic properties of graphene functionalized with noble metals was also discussed. The studies presented in this review were carried out in order to understand how the metalsupport interaction drives chemical catalysis. The preparation technique, the type and amount of metal, the nature of the support, the type of dopant and the technique of applying the catalyst, all these are dependent on the metal-support relationship. Following this review, it was found that the noble metals demonstrated a special efficiency in the electrocatalytic activity and the electrochemical stability of the compounds based on carbon and graphene oxide. It was also observed that to improve the oxygen reduction reaction (ORR) and the quality of hydrogen adsorption and desorption, a higher electrochemical active surface area (ECSA) of the noble metal catalyst is required. The uniform distribution and surface morphology of noble metal nanoparticles on rGO were found to have an effect on the ORR. Most applications of noble metal functionalized graphene are in fuel cells, renewable energy (photovoltaic, green hydrogen production) and supercapacitor applications.

Conclusions
This review presents the most used and up-to-date methods for the synthesis of graphene functionalized with noble metals (Pt, Ag, Pd and Au) as well as the relevant methods for the characterization of catalysts. The potential of capitalizing on the improved catalytic properties of graphene functionalized with noble metals was also discussed. The studies presented in this review were carried out in order to understand how the metal-support interaction drives chemical catalysis. The preparation technique, the type and amount of metal, the nature of the support, the type of dopant and the technique of applying the catalyst, all these are dependent on the metal-support relationship. Following this review, it was found that the noble metals demonstrated a special efficiency in the electrocatalytic activity and the electrochemical stability of the compounds based on carbon and graphene oxide. It was also observed that to improve the oxygen reduction reaction (ORR) and the quality of hydrogen adsorption and desorption, a higher electrochemical active surface area (ECSA) of the noble metal catalyst is required. The uniform distribution and surface morphology of noble metal nanoparticles on rGO were found to have an effect on the ORR. Most applications of noble metal functionalized graphene are in fuel cells, renewable energy (photovoltaic, green hydrogen production) and supercapacitor applications.